Source: Environmental Protection OnLine
A new study conducted by UC Berkeley researchers states that diesel exhaust is responsible for fifteen times more secondary organic aerosol (SOA), a major component of smog, than gas emissions per liter of fuel burned.
The study performed by UC Berkeley researchers, which has been published in the Proceedings of the National Academy of Sciences, states that the contributions to air pollution are derived from two types of fuel emissions. The authors estimate that diesel exhaust is responsible for 65-90 percent of a region’s vehicular-derived SOA, depending upon the relative amounts of gasoline and diesel used in the area.
SOA contributes to respiratory problems and poor air quality, so pinpointing the major sources of the pollutant is important in evaluating current and future policies to reduce smog in the state. The new findings contradict previous research that put the blame on gasoline-fueled vehicles as the predominant source of precursors that form secondary organic aerosol.
“We can now say that, while both motor vehicle sources are important for these ‘secondary’ particles, diesel is responsible for a larger portion, especially in regions such as the San Joaquin Valley with a lot of diesel use,” said study principal investigator and professor Allen Goldstein, who has joint appointments in the Department of Environmental Science, Policy and Management and the Department of Civil and Environmental Engineering.
“The data from our study contains the most comprehensive chemical detail to date on diesel and gasoline emissions,” said study lead author Drew Gentner, a recent UC Berkeley Ph.D. graduate in civil and environmental engineering. “This presents many opportunities to assess the chemistry of these compounds in the atmosphere and the impacts of these sources. We expect that these findings will help policymakers improve air pollution control measures in the state, and also other parts of the world.”
Emissions from gasoline and diesel vehicles are predominant anthropogenic sources of reactive gas-phase organic carbon and key precursors to secondary organic aerosol (SOA) in urban areas. Their relative importance for aerosol formation is a controversial issue with implications for air quality control policy and public health. We characterize the chemical composition, mass distribution, and organic aerosol formation potential of emissions from gasoline and diesel vehicles, and find diesel exhaust is seven times more efficient at forming aerosol than gasoline exhaust. However, both sources are important for air quality; depending on a region’s fuel use, diesel is responsible for 65% to 90% of vehicular-derived SOA, with substantial contributions from aromatic and aliphatic hydrocarbons. Including these insights on source characterization and SOA formation will improve regional pollution control policies, fuel regulations, and methodologies for future measurement, laboratory, and modeling studies.